10.6084/m9.figshare.1011580.v1
Christopher K Gilmore
Christopher
K Gilmore
Steven R H Barrett
Steven
R H Barrett
Jamin Koo
Jamin
Koo
Qiqi Wang
Qiqi
Wang
Pathways of O<sub>3</sub> production and loss considered in the chemical pathway analysis
IOP Publishing
2013
aviation NOx emissions
O 3 burden
Pacific aviation emissions
O 3
tropospheric O 3
cause 157 times
O 3 production
aviation NOx
tropospheric ozone formation
North American emissions
chemical pathway analysis
O 3 formation
Abstract Aviation NOx emissions
Environmental Science
2013-09-04 00:00:00
Dataset
https://iop.figshare.com/articles/dataset/___Pathways_of_O_sub_3_sub_production_and_loss_considered_in_the_chemical_pathway_analysis/1011580
<p><b>Table 1.</b>
Pathways of O<sub>3</sub> production and loss considered in the chemical pathway analysis.
</p> <p><strong>Abstract</strong></p> <p>Aviation NO<sub><em>x</em></sub> emissions promote tropospheric ozone formation, which is linked to climate warming and adverse health effects. Modeling studies have quantified the relative impact of aviation NO<sub><em>x</em></sub> on O<sub>3</sub> in large geographic regions. As these studies have applied forward modeling techniques, it has not been possible to attribute O<sub>3</sub> formation to individual flights. Here we apply the adjoint of the global chemistry–transport model GEOS-Chem to assess the temporal and spatial variability in O<sub>3</sub> production due to aviation NO<sub><em>x</em></sub> emissions, which is the first application of an adjoint to this problem. We find that total aviation NO<sub><em>x</em></sub> emitted in October causes 40% more O<sub>3</sub> than in April and that Pacific aviation emissions could cause 4–5 times more tropospheric O<sub>3</sub> per unit NO<sub><em>x</em></sub> than European or North American emissions. Using this sensitivity approach, the O<sub>3</sub> burden attributable to 83 000 unique scheduled civil flights is computed individually. We find that the ten highest total O<sub>3</sub>-producing flights have origins or destinations in New Zealand or Australia. The top ranked O<sub>3</sub>-producing flights normalized by fuel burn cause 157 times more normalized O<sub>3</sub> formation than the bottom ranked ones. These results show significant spatial and temporal heterogeneity in environmental impacts of aviation NO<sub><em>x</em></sub> emissions.</p>